本研究對(duì)中國(guó)中部地上河地區(qū)地下水中橡膠添加劑及相關(guān)氧化產(chǎn)物（RAROPs）的存在情況進(jìn)行了調(diào)查。檢測(cè)出了7種RAROPs，其在淺層地下水中的含量從黃河附近區(qū)域（平均值：8.49 ng L-1）到黃河遠(yuǎn)岸區(qū)域（平均值：5.01 ng L-1）呈輕微下降趨勢(shì)。相比之下，深層地下水中RAROPs的含量急劇下降，僅為0.26 ng L-1。發(fā)現(xiàn)主要污染物為N-（1,3-二甲基丁基）-N'-苯基-對(duì)苯二胺（6PPD）。

車庫(kù)和停車場(chǎng)附近常被視為污染熱點(diǎn)區(qū)域。相關(guān)性分析進(jìn)一步表明，水產(chǎn)養(yǎng)殖可能是淺層地下水污染物輸入的潛在途徑。由于城鄉(xiāng)發(fā)展不平衡，人類通過地下水?dāng)z入的RAROPs量相差近30倍。兒童最容易受到RAROPs的侵害。因此，人類活動(dòng)（交通運(yùn)輸、廢舊輪胎儲(chǔ)存、水資源分配與利用模式、黃河水引入養(yǎng)殖池塘）可能會(huì)通過地表土壤淋濾污染物，加劇地下水中RAROPs的污染。這些結(jié)果對(duì)于發(fā)展中國(guó)家制定適宜的地下水資源利用與保護(hù)策略具有重要意義。 

Each 300 mL of groundwater sample was filtered through precleaned 0.7 um GF (glass microfiber filter)/F membranes. Then, filtrateswere extracted by high flux automatic solid-phase extractor (FotectolPlus, RayKol Group Corp., Ltd., Xiamen, china) with Oasis hydrophiliclipophilic balanced (HLB) solid-phase extraction (SPE) cartridges (500mg6 mL1), following the proceduredescribed below.

Each cartridge was sequentially pre-conditioned with 10 mL ofmethanol and 10 mL of deionized water. After that, the filtrates wereloaded onto the cartridge at a flow rate of approximately 1.5 mL min-1The cartridge was then rinsed with 10 mL of mixed solvent (equalamount of methanol and deionized water by volume) and dried undernitrogen gas for 30 min. After drying, the analytes were eluted from theHLB cartridge using 15 mL methanol and 10 mL acetonitrile. The elutionwas finally evaporated to 0.5 mL, before being diluted to a final amountof 1 mL using deionized water for analysis using ultra-high-performanceliquid chromatography and mass spectrometry (UHPLC-MS/MS).

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